• 专利附录
  • 专利说明
  • 权利要求
  • 类似技术
  • 同族专利
  • 引用文献
  • 法律状态
  • 优先权
    • 专利摘要:
    The invention relates to a method for treating a lignocellulosic biomass, with: a. Pretreatment of the biomass by at least one cooking or steam explosion operation, in order to obtain a pretreated substrate, b. Liquid / solid separation on at least part of the pretreated substrate, comprising two successive substeps: - an upstream substep of contacting b1 of the solid / liquid mixture implemented by a continuous mixer (M) using a mixing fluid a downstream extraction / washing sub-step b2 implemented by a continuous filter, using a washing fluid, to obtain a solid phase enriched in solid and a plurality of liquid phases enriched in liquid, with at least recycling partial of a liquid phase extracted from the filter entering the mixer as a mixing fluid.
    公开号:FR3083126A1
    申请号:FR1855789
    申请日:2018-06-27
    公开日:2020-01-03
    发明作者:Caroline Aymard；Emilia KNOSPE；Romain Rousset；Larissa PEROTTA
    申请人:IFP Energies Nouvelles IFPEN；Institut National de la Recherche Agronomique INRA；Agro Industrie Recherches et Developpements ARD；
    IPC主号:
    专利说明:

    LIGNO-CELLULOSIC BIOMASS TREATMENT PROCESS
    Field of the invention
    The invention relates to a process for treating lignocellulosic biomass to produce so-called second generation (2G) sweet juices. These sweet juices can be used to produce other products chemically or biochemically / fermentatively (for example, alcohols such as ethanol, butanol or other molecules, for example solvents such as acetone and d 'other bio-based molecules ...).
    Prior art
    Lignocellulosic biomass represents one of the most abundant renewable resources on earth. The substrates considered are very varied, they relate both to woody substrates such as different woods (hardwoods and conifers), by-products from agriculture (wheat straw, rice straw, corn cobs, etc.) or other food, paper, etc. industries Lignocellulosic biomass is made up of three main polymers: cellulose (35 to 50%), which is a polysaccharide essentially made up of hexoses; hemicellulose (20 to 30%), which is a polysaccharide essentially consisting of pentoses; and lignin (15 to 25%), which is a polymer of complex structure and of high molecular weight, composed of aromatic alcohols linked by ether bonds. These different molecules are responsible for the intrinsic properties of the plant wall and are organized into a complex tangle. Among the three basic polymers which integrate lignocellulosic biomass, cellulose and hemicellulose are those which allow the production of 2G sweet juices.
    The biochemical transformation process of lignocellulosic into 2G sweet juices notably includes a pre-treatment step and an enzymatic hydrolysis step with an enzymatic cocktail. These processes also most often include an impregnation stage before the pretreatment. The sugary juices from hydrolysis can be used / developed as such or optionally be further processed, for example in a fermentation or chemical process. Most often, the overall process comprises intermediate separation steps and / or a step of purifying the final product.
    The pretreatment makes it possible to modify the physicochemical properties of the lignocellulosic biomass in order to make the cellulose accessible to the enzymes and to achieve good reactivity in enzymatic hydrolysis. Numerous pre-treatment technologies exist and allow the biomass to be heated up under various chemical conditions. The pretreatment can be carried out with or without the addition of acidic or basic products. It can also be carried out in a solvent such as water or an organic product such as, for example, alcohol (organosolv process) but also in a low-diluting medium such as steam. This pretreatment can also have a physical step such as defibration or an explosive expansion in the context of a steam explosion. This pretreatment can also have several stages making it possible to optimize the overall process, such as, for example, an acid cooking followed by a steam explosion or two consecutive steam explosions. The pretreatments below grouped under the generic term "cooking" relate to treatments under dilute conditions of the biomass, and group together acid cooking, alkaline cooking, and "organosolv" cooking. This latter process relates to a pretreatment in the presence of one or more organic solvents and generally of water. The solvent can be an alcohol (ethanol), an acid such as acetic acid, formic acid, or acetone. The organosolv pulping processes lead to an at least partial solubilization of the lignin, a partial solubilization of the hemicelluloses. There are then two output streams: the substrate pretreated with residual cellulose, hemicellulose and lignin and the solvent phase which contains the solubilized line and part of the hemicellulose. There is generally a regeneration step for the solvent which makes it possible to extract a stream of lignin. Certain “organosolv pulping” treatments (in particular with ethanol) are combined with the addition of a strong acid (of the H 2 SO 4 type ). It is also possible to envisage having the biomass in contact with the solvent via an impregnation reactor before the cooking phase or having the biomass in contact with the acid catalyst before cooking " organosolv pulping '.
    Explosion-type pre-treatment with steam is different from cooking-type treatment in that the biomass is concentrated and subjected to a proportionally small amount of water vapor. Most often, the steam explosion in acidic condition is preferred, because it allows a good compromise between the acid hydrolysis of hemicellulose and the reactivity of cellulose in enzymatic hydrolysis, with an almost total hydrolysis of hemicellulose. and a significant improvement in the accessibility and reactivity of cellulose to enzymes. This pretreatment can be preceded by other treatment (s) (grinding, impregnation, cooking, etc.).
    Different configurations are reported for example in the document “Production and bioethanol from lignocellulosic materials via the biochemical pathway: A review”, M. Balat, Energy Conversion and Management 52 (2011) 858-875, or even in the document “Bioethanol production from agricultural wastes: an overview ”, N. Sarkar, S. Kumar Ghosh, S. Bannerjee, K. Aikat, Renwable Energy 37 (2012) 19-27.
    It is therefore noted that this type of process, cooking or steam explosion, requires a transformation of the raw biomass into a reactive pretreated substrate (also called pretreated marc), before starting the following conversion steps proper. After this pretreatment, sugars (sugars in C5 and C6) are found in a sweet juice permeating the pretreated marc. The recovery of this juice could be interesting for recovery in the rest of the biomass transformation process or in another process (in parallel) or for marketing as such sweet juice. There is therefore an advantage in extracting these juices from the pretreated marc, before the pretreated marc in question, which will then be enriched in solid matter, undergoes the following treatments.
    The pretreatment step is often preceded by an impregnation step. It is followed by an enzymatic hydrolysis step using an enzymatic cocktail. In certain cases, these preceding stages are followed by a stage of ethanolic fermentation of the released sugars and of a stage of purification of the fermentation products. Under certain configurations of the process diagram, the enzymatic hydrolysis and fermentation stages can take place in the same reactor, in a fermentation configuration called SSF (Simultaneous Saccharification and Fermentation). When these two process steps are separated, this is called a SHF (Separated Hydrolysys and Fermentation) type scheme. Examples are given by the document Ethanol from lignocellulosics: A review of the economy, M. von Silvers and G. Zacchi, Bioresource Technology 56 (1996) 131-140.
    Also in these stages, one can have products in the form of a solid / liquid mixture, for example the so-called hydrolysate products obtained after the enzymatic hydrolysis, where it may be advantageous to effect a solid / liquid separation, to extract the phase liquid, for example to use the juices produced in a later stage sensitive to the presence of solid, for example in case of sensitivity of the fermentative microorganism used in a later stage of fermentation, or in case of recycling of the microorganism around this fermentation stage.
    It can therefore be seen that at different stages of the biomass treatment processes, we are dealing with products in the form of solid / liquid mixtures, and that it may be advantageous to extract at least part of the liquid phase from the solid phase with a view to enhancing it and optimizing the overall process.
    Patent WO 2014/135755 proposes a process for the treatment of biomass with the following sequence of steps: a- a pretreatment step is carried out by bringing the biomass charge into contact and heating with water and an acidic compound or basic, so as to obtain a pretreated substrate, b- the pretreated substrate is brought into contact with cellulase enzymes and with a liquid stream enriched in fermentation products obtained in step e) so as to obtain a hydrolyzate comprising a solid residue and a liquid phase containing sugars, c- an alcoholic fermentation of the hydrolyzate is carried out by means of an alcohologenic microorganism so as to produce a fermentation wine comprising a solid material and a liquid phase containing fermentation products, d- at least a portion of the solid matter contained in the fermentation wine is extracted so as to obtain a stream enriched in solid matter and an impoverished fermentation wine i in solid material, e- the stream enriched in solid material is washed with a liquid stream so as to obtain said liquid stream enriched in fermentation products, the liquid stream enriched in fermentation products being recycled in step b), f - A step of separation of the fermentation wine depleted in solid material is carried out so as to obtain at least one purified flow comprising an alcohol or a solvent and at least one flow of vinasse.
    This patent thus proposes to effect the separation of lignin and other possible inert solids after the fermentation step. The solid material composed mainly of lignin is then subjected to washing to recover the trapped fermentation products, in particular alcohols and solvents. The washing liquid is then recycled to the enzymatic hydrolysis unit, which can be the same unit as the fermentation unit or which can be separate from the fermentation unit so as not to dilute the existing streams .
    Patent EP 2 774 992 proposes to carry out, in a process comprising a pretreatment step, an enzymatic hydrolysis step and then a fermentation step, to extract at least part of the solid residue contained in the hydrolyzate so as to obtaining a stream of solid residue comprising lignin and a hydrolyzate depleted in solid residue, then the stream of solid residue is washed with a liquid stream so as to recover a liquid stream enriched in sugars, which can be recycled in step d enzymatic hydrolysis to be able to develop the sugars without bringing any dilution of the flows in the process.
    In these two patents, therefore, washes and extractions of intermediate products are carried out, aiming to separate from a solid / liquid mixture a phase enriched in solid material and a phase enriched in liquid, using conventional devices such as a decantation or percolation to carry out extraction / separation and a backwashing device.
    However, achieving such a solid / liquid separation is a delicate operation to standardize, since the mixture can have very different characteristics, both, in particular, depending on its place in the sequence of steps of the overall treatment process. of the biomass, depending on the type of biomass used, etc. These characteristics are in particular the dry matter content of the initial biomass or the rheology of the mixture to be treated. The purpose of the separation may also differ, depending on how far one wants to push the separation. Conventional devices do not necessarily have all the flexibility and performance required to provide separations on such different mixtures.
    The object of the invention is therefore to devise a new way of carrying out solid / liquid separations from a mixture, which is improved compared to conventional technologies, in particular in the context of biomass treatment processes. It aims in particular to design more efficient and / or more flexible technologies depending on the mixture to be treated.
    Optionally, the invention aims to design this type of technology which, moreover, can be implemented with devices as compact as possible.
    Summary of the invention
    The subject of the invention is first of all a process for treating a lignocellulosic biomass, said process comprising at least the following step:
    at. Pretreatment of the biomass by at least one cooking or steam explosion operation, in order to obtain a pretreated substrate.
    This method also includes at least one step of:
    b. Liquid / solid separation on at least part of the pretreated substrate obtained at the end of step a or at the end of an additional step of treatment of said substrate after step a, said separation step comprising two sub- successive steps:
    an upstream sub-step of contacting b1 of the solid / liquid mixture implemented by a continuous mixer using a mixing fluid, optionally preceded by a pump, and a downstream sub-step b2 of extraction / washing implemented by a continuous filter, in particular of the band filter type, using a washing fluid, to obtain a solid phase enriched in solid and a plurality of liquid phases enriched in liquid, with an operation of the filter preferably in counter-current between the circulation of the solid / liquid mixture to be separated and the extraction / washing fluid, and at least partial recycling of a liquid phase extracted from the band filter at the inlet of the mixer as mixing fluid.
    Throughout the present text, the terms "upstream", "downstream", "next" or "previous" are made with reference to the general flow direction of the product to be treated in question, of the solid part of the biomass to be treated for be more precise, in the installation implementing the method of the invention.
    To carry out the solid / liquid separation, the invention thus proposes to couple two operations with two devices specific to each of them, namely firstly a mixer for bringing the mixture to be separated into contact with a mixing fluid (aqueous by example), which can operate continuously, and which then feeds a band filter to effect the actual separation. The mixer gives the mixture the appropriate characteristics (rheological properties, dry matter content, etc.) so that it can then be treated by the filter continuously. The two devices can be connected in series, both operating continuously, which is significantly more advantageous than batch operation. For the filter, the term "continuous" is understood for the solid to be treated.
    The continuous mixer is known in principle: it is, schematically, a mixer comprising a cylindrical hollow body with an inlet supplied with the mixture, an internal screw for conveying the mixture from the inlet to the outlet of the mixer, and a mixing fluid circuit (water) bringing the mixture in the mixer into contact with the fluid in question. The mixer can be fitted with a doser at the inlet. This type of continuous mixer is notably marketed by PARIMIX under the name "PARIMIX IMR continuous mixer". It has in particular the advantage of being able to operate the contacting of a mixture, even at high flow rate, with a small volume of mixing chamber, which makes the device very compact, which is very particularly sought in the context of invention. It also allows a short residence time of the mixture in the mixer, while making it possible to obtain, at the outlet of the mixer, a very homogeneous product and at the desired dry matter content.
    The preferred continuous filter is a band filter, also known in principle: schematically, it makes it possible to carry out the extraction and washing of a solid / liquid mixture continuously, by conveying the mixture to different zones successively of a canvas band. The extraction is done under partial vacuum through this fabric which transports the mixture, from zone to zone, and which is porous in order to be able to carry out filtration / extraction. It can be fitted, in its most downstream part, with a press to complete the extraction of the liquid. This type of band filter is for example marketed by the company BHS under the name "Continuous band filter BFR".
    Other continuous filters can also be used, for example in the form of a belt press or in the form of a plurality of belt presses in series.
    The invention therefore uses in series these two devices, both operating continuously (the band filter operating, however, strictly speaking sequentially, as will be detailed below), the output of the mixer feeding the input of the filter (this which is clearly more advantageous than a batch operation), hence a very compact assembly which is easy to integrate into an existing biomass processing installation.
    What the invention discovered is that the combination of two choices of operating parameters of these devices was the necessary condition for the separation obtained to be industrially feasible first, and for it to be as robust and efficient:
    - on the one hand, the choice of a continuous filter operation, in particular a band filter and preferably operating in counter-current between the circulation of the solid / liquid mixture to be separated and the extraction fluid / washing (the counter-current operation having proved to be more efficient than a co-current operation,
    on the other hand, at least partial recycling of a liquid phase extracted from the filter at the inlet of the mixer as a mixing fluid, which has made it possible to reduce the consumption of mixing fluid, generally water, of the mixer , and which has surprisingly been found to allow both more efficient mixing at the level of the mixer and extraction of liquid phase (s) at the level of the more concentrated filter (s).
    Preferably, the separation of the solid / liquid mixture during step b is carried out on a first part of the pretreated substrate obtained at the end of step a, and a second part of said pretreated substrate is subjected to at least one step. subsequent treatment, in particular hydrolysis and then fermentation, and the solid phase enriched in solid obtained in step b is also subjected to at least one subsequent treatment step, in particular the same or the same as those undergone by the second part of the pretreated substrate.
    It is thus possible to extract a part of the liquid from the pretreated marc, the whole from the simply pretreated marc and from the pretreated marc then separated according to the invention then following the same sequence of steps, and being for example injected into the same reactor of the next step to undergo the same transformation.
    The interest is then to be able to withdraw just a part of the liquid phase (just the sufficient quantity) from a part of the pretreated marc, with a view to recovery or exploitation in the process itself of the liquid phase containing sugars (also called "Sweet juice" in this text).
    Advantageously, according to one embodiment, the liquid phases enriched in liquid resulting from the separation step b are sweet juices, and said method also comprises a step c for producing enzymes and / or a step d for producing yeasts , and at least one of said sweet juices is used for said production of enzymes c or yeasts d (propagation / growth of microorganisms). It is thus possible, in this case, to extract just the necessary quantity of sweet juice to supply the production of enzymes or yeasts, and thus limit the separation of the pretreated marc to the just necessary.
    The method according to the invention may advantageously comprise a step e of enzymatic hydrolysis of the pretreated substrate resulting from step a of pretreatment to obtain a hydrolyzate, and the solid / liquid separation b can then be carried out on at least part of said hydrolyzate , especially on all of said hydrolyzate.
    According to one embodiment, the solid / liquid separation b is carried out on at least a part, in particular all, of the pretreated substrate obtained at the end of the pretreatment step a to obtain a solid phase enriched in solid, and the process also comprises a step e of enzymatic hydrolysis of said solid phase enriched in solid to obtain a hydrolyzate. In this case, it is therefore preferable to separate all of the pretreated marc and to use all the extracted liquid phase, which is advantageous when the production of sugary juice is specifically aimed at developing it separately from the rest of the process.
    Advantageously, the method according to the invention also comprises the following steps after step a of pretreatment:
    e. Enzymatic hydrolysis of the pretreated substrate, in order to obtain a hydrolyzate comprising a solid matter and a liquid phase containing sugars,
    f. Fermentation of the hydrolyzate, in order to obtain a fermentation wine, stage f of fermentation being able to succeed or be concomitant with stage e of enzymatic hydrolysis
    g. Separation / distillation of the fermentation wine, in order to obtain a distillation product in the form of an alcohol, a solvent, or other biobased molecule, and vinasses, step b of separation can be carried out on at least one part, in particular all, of the products obtained after the hydrolysis step e and / or fermentation step and / or g / separation / distillation.
    Optionally, in step b of separation, the interior of the mixer is heated to a temperature of at least 30 ° C in operation, in particular between 40 and 60 ° C, in particular by integrated electric heating means. It has indeed been found that heating the mixture during its transport inside the mixer improves the homogeneity of the mixture leaving the mixer. Temperatures remain low enough not to generate too much energy consumption.
    More preferably, in step b of separation, the extraction / washing fluid is heated before introduction into the filter and / or the liquid phase extracted from the filter and recycled before its introduction into the mixer, in particular to a temperature of at least 30 ° C, and at most 90 ° C, in particular a temperature between 40 ° C and 80 ° C. Heating the liquid phase before recycling it in the mixer allows it to participate in the effort of heating the mixture in the mixer. The heating obtained by the heating means equipping the mixer and the heating obtained by the circulation in the mixer of a hot mixing fluid can then be adjusted appropriately. Naturally, it is also possible to heat the mixing fluid not originating from recycling from the filter (generally water), in addition to or instead of heating the liquid phase recycled from the filter.
    Advantageously, in step b, the filter is a band filter which comprises at least two, in particular at least three, successive zones, with drawing off in at least one, in particular in each, zone of a liquid phase. The band filters are very flexible to use: we can predict the number and the dimension, in particular the length of zones that we want, we can group zones to draw only one liquid phase by grouping zones , the zones can have different lengths, for example increasing or decreasing lengths depending on the axis of transport of the mixture on the strip ...
    Preferably, the liquid phase of the first and / or of the second zone is recycled at least partially at the inlet of the mixer of step b. It is therefore preferred to recycle the liquid phase (s) extracted most upstream from the band filter, that is to say those which are the most concentrated, which makes it possible to obtain a more concentrated liquid at the outlet of the mixer. Preferably, the liquid phase withdrawn from the third and / or the following zones and / or from the last zone is recycled at least in part as washing / extraction fluid from the band filter: this is the way in which implement the counter current in the operation of the band filter in the invention.
    Optionally, in step b, the filter, in particular the band, can be fitted with a press in its terminal part. The separation is thus further improved.
    Advantageously, the operating parameters of the separation steps b1 and b2 can be selected according to the characteristics of the solid / liquid mixture, so that the liquid phases produced extracted from the band filter have a concentration of at least 50 g of product / kg, in particular at least 50 g of sugar / kg when separation b is carried out on the pretreated substrate resulting from step a of pretreatment. It is indeed from such a concentration that sugary juices can be effectively valorized as such.
    The subject of the invention is also an installation for processing a lignocellulosic biomass, in particular intended for implementing the method described above, and which comprises at least:
    - a biomass pretreatment zone by at least one cooking or steam explosion operation, in order to obtain a pretreated substrate,
    a liquid / solid separation zone on at least part of the pretreated substrate obtained at the exit from the pretreatment zone or from an additional zone for treating said substrate after the pretreatment zone, said separation zone comprising two sub-zones in series: - an upstream contacting sub-zone comprising a continuous mixer using a mixing fluid, possibly associated with an upstream pump, and - a downstream extraction / washing sub-zone comprising a continuous filter, in particular of the filter type belt with a washing fluid, with a filter operation preferably against the current between the circulation of the solid / liquid mixture to be separated and the extraction / washing fluid, and at least partial recycling of an extracted liquid phase by the band filter at the inlet of the mixer as a mixing fluid.
    The installation may provide, in the separation zone: - fluid connection means between the band filter and the mixer to recycle at least part of a liquid phase extracted by the filter at the inlet of the mixer and - means of fluid connection to recycle another liquid phase extracted from the filter as washing fluid for said filter.
    The filter is preferably a band filter, which can optionally be fitted with a press in its terminal part.
    The treatment installation may also include an enzyme production zone and / or a yeast production zone, and provide means for transferring at least one liquid phase extracted from the band filter from the separation zone to the enzyme production zone and / or yeast production zone, said liquid phase being a sweet juice.
    The subject of the invention is also the use of the method or of the installation described above for the treatment of biomass of the wood, straw, agricultural residue type, and all dedicated energy crops, in particular annual or multi-annual plants such as miscanthus. to produce sugars, biofuels or biobased molecules. More generally, the lignocellulosic biomass, or lignocellulosic materials used in the process according to the invention is obtained for example from wood (hardwoods and resinous), raw or treated, from agricultural byproducts such as straw, fibers from plants, forest crops, residues of alcoholic, sugar and cereal plants, residues from the paper industry, marine biomass (for example cellulosic macroalgae) or products of transformation of cellulosic or lignocellulosic materials. The lignocellulosic materials can also be biopolymers and are preferably rich in cellulose.
    The invention makes it possible to produce, as recoverable products, both biofuel such as ethanol and sugary juices, or only biofuel, or only sugary juices, with great flexibility.
    detailed description
    The invention will be detailed below with the aid of nonlimiting examples illustrated by the following figures:
    Figure 1: a block diagram of the tools used in the context of the invention to perform step b of separation of a solid / liquid mixture in a biomass treatment process;
    Figures 2a and 2b: two different operations of the tools shown in Figure 1, depending on the type of biomass used;
    Figure 3: a schematic representation (longitudinal cross section) of the mixer belonging to the tools shown in Figure 1;
    Figure 4: a functional representation in the form of a block diagram of the separation step b operated by the invention integrated into a biomass pretreatment step according to a first variant;
    Figure 5: a functional representation in the form of a block diagram of a complete biomass treatment process integrating the separation step b operated by the invention according to Figure 4;
    Figures 6,7,8: a functional representation in the form of a block diagram of a complete biomass treatment process integrating the separation step b operated by the invention according to a second, third and fourth variant respectively.
    Description of the figures
    The same references corresponding to the same components / fluids / products in all of the figures. The figures are very schematic, are not necessarily to scale and do not represent all the components of the tool, all the details of the processes concerned, but only those of particular interest to the description of the invention.
    FIG. 1 therefore represents the tools developed within the framework of the invention for effecting the solid / liquid separation of a mixture in a process for treating lignocellulosic biomass: the mixture to be separated is first treated by a mixer M continuous type IMR from PARIMIX, shown in more detail in FIG. 3, then by a band filter F of the type continuous band filter under vacuum, of the type BFR from BHS. They are both here arranged substantially horizontally, at different heights, the mixer being arranged above the band filter.
    To simplify the description of these tools, for the sake of brevity, it will be considered that the mixture to be separated is a marc pretreated from a biomass treatment process, although the separation according to the invention can be applied to other solid / liquid mixtures of such a process (as described below with the aid of Figures 6 and following).
    The mixer M allows a repulping of the pretreated marcs with a high dry matter (MS) and solid content, by adding a mixing fluid and by kneading obtained by the endless turn of the mixer conveying the marc from one end to the other from the mixer. The mixer M, as detailed in FIG. 3, comprises a cylindrical body provided with a rotating screw V without a core, with its upstream end provided with a doser D continuously dosing the mixture to be separated, which is then injected into the mixer by a feed tube or hopper A connected to the dispenser. It is shown in the operating position, that is to say in a substantially horizontal plane.
    In its upstream part, the cylindrical body of the mixer is provided with inlet (s) of mixing fluid (s) e1, e2, the fluid (s) are centrifuged by the turns, the liquid vortex thus created meets the flow of exploded grounds reverse. Thanks to this principle, the volume of the mixing chamber of this mixer is low, the power used is also low and the mixer as a whole is compact. Here, the mixer is equipped with electric heating means (not shown) for heating the interior of the cylindrical body to a temperature of about 40 to 50 ° C., this supply of heat favoring obtaining greater homogeneity of the mixing at the outlet of the mixer with a constant residence time therein. The plumped marc, at the outlet of the mixer M, falls by gravity onto the upstream part of the band of the band filter F.
    The separation of this residue on the F-band filter with backwashing makes it possible to extract juices concentrated in sugars. The technology of the F band filter is based on vacuum filtration, the principle of which is to distribute the pretreated marc on a band advancing sequentially. This porous strip makes it possible, by vacuum drawing, to separate the liquids (the juices) from the solid by forming a cake (the washed marc), which falls at the end of the strip. Washing fluid is sprayed over the strip to wash the cake which gradually forms along the strip. The juices are partially recycled, as detailed below. They can also be grouped into a single stream.
    In this example, the band filter F has 10 active vacuum zones, numbered 1 to 10 in FIG. 1, where different stages of the washing and filtration process can take place (displaceable and resizable zones in the filter). It can be fitted with polyurethane or silicone type polymer strips on the side of the filter strip to limit vacuum losses and improve separation. One can plan to add a partition in the upper part (or any other equivalent mechanical means), just after the first zone or zones, to allow a better distribution of the mixture on the strip.
    We now describe the different flows entering and leaving these devices, from upstream to downstream: the pretreated marc MO enters the doser D of the mixer M, while the mixing fluid is introduced into the mixer through the inputs e1 , e2 (shown in Figure 3). The mixed marc M1 (also designated “MoRe” below) leaves at the downstream end of the mixer M and falls by gravity to the band B of the filter F in its upstream part. The strip conveys the marc to its downstream end, with vacuum extraction, under the strip, of three liquid phases J1, J2 and J3, which are sweet juices of decreasing concentrations. Above the strip, in its upstream or central part, two fluids f1 and f2 are extracted / washed by nozzles remote from each other. The fluid f1 can be water, the fluid f2 is the partial or total recycling of the juice J3.
    It naturally remains within the framework of the invention to extract under vacuum not three liquid phases, but more, at most the same number as zones in the band filter.
    The extraction / washing fluid moves against the flow of the mixture on the strip. In the context of the present invention, it is in fact, in known manner, a “simulated” counter-current, in the sense that there is no counter-current flow proper in each of the washing areas. The principle of the band filter is based on a tangential washing: the mixture here moves laterally, in the figure by way of example from left to right, and the washing liquid (called higher extraction / washing fluid more general) moves from top to bottom. The injection of liquid on the mixture which moves on the strip can be done, in particular, either by pouring, that is to say by gravity flow, or by sprinkling ... The movement from top to bottom of the liquid passing through the mixture moving on the strip is imposed by the vacuum that is created on the strip. The filter operates sequentially on the mixture comprising the solid phase to be extracted (also called “cake”), which can be schematized as follows: - time 1, the band advances, time 2, the band stops and the vacuum is created (and if necessary, pressed) and juice is extracted in each of the zones, and so on. It should be noted, generally, that the injection of washing liquids is carried out continuously (it is injected when the belt advances and when it is stopped). The countercurrent is "simulated" by the reinjection of the extracted juice upstream of its extraction.
    All or part of at least one of the juices J1, J2, J3 can be recycled as mixing fluid in the mixer M.
    Under the 10 zones of the porous band of the filter F, there are therefore extracted under partial vacuum here three liquid phases denoted J1, J2 and J3, while the solid phase progressively enriched in solid, the "cake" G, continues its course until partly downstream of the strip, from which it is extracted after being subjected to a press P arranged at the very end of the strip, press which ends the separation. This pressing step is optional.
    The washing fluid (s) f1, f2 are heated, for example to a temperature of 30 to 85 ° C before being poured onto the top of the cake conveyed by the porous strip, using heating means equipping the conduits feed.
    The flow of sugary juice (s) which is recycled either as a mixing fluid in the mixer or as a washing / extraction fluid in the filter is / are also heated before reintroduction into the filter or in the mixer, also at using heating means equipping their supply ducts, for example at a temperature of 30 to 85 ° C.
    FIG. 2a represents a first way of implementing the installation of FIG. 1, to separate the pretreated marc from a biomass based on Miscanthus: the J3 juice is entirely recycled in the most upstream inlet, the inlet f1, washing fluid extracting the filter F, the juice J2 is entirely recycled at the inlet e1 of the mixer M, in addition to an inlet e2 of the mixing fluid in the form of water. All the J1 juice is extracted for use / recovery outside this separation facility.
    FIG. 2b is another way of implementing the installation of FIG. 1, for separating the pretreated marc from a biomass based on straw. The difference from Figure 2a is that here part of the juice J1 is also recycled as a mixing fluid in the mixer with the juice J2.
    The proportion of each of the juices J1, J2, J3 ... extracted from the band filter which is recycled in the mixer or in the filter can be very variable, from 0% to 100%. It will depend on the nature of the biomass (the rate of its dry matter), the desired water consumption, the desired concentration of active agents (in sugars here) of the juices extracted according to their subsequent use, in a process global biomass treatment, as required, or as an independent recovery product.
    FIG. 4 represents the integration of the separation step b into a biomass pretreatment in the form of a block diagram. The references represented have the following meaning:
    1. Biomass to be treated
    2. Pretreatment step
    3. Fluid flow required for pretreatment of biomass (water, acid catalyst, steam,)
    4. Pretreated marc stream, separated into two streams 4a which goes to the separation step b and 4b (which goes to the hydrolysis step as detailed below using FIG. 5)
    5. Mixer used in step b of separation according to the invention
    6. Mixing at the outlet of the mixer
    7. Band filter separator used in step b of separation according to the invention
    8. Washing fluid (usually water)
    9. Sweet juice extracted
    10. Solid washed
    11. Intermediate juices which are returned to the belt filter and at least part of which (11a) is sent to the mixer
    Block 2 is the first stage of conditioning and pretreatment of an incoming flow of biomass 1 with one or more reagents, by bringing it into contact with one or more other incoming flows 3 of fluid (water, water with an acid type chemical catalyst, basic, oxidizing, water vapor ...) and possible heat treatment (s). In outgoing flow, we obtain a pretreated marc flow 4.
    The block 5 therefore operates the sub-step b1 of the separation b according to the invention: it is the mixer M which receives as input a portion 4a of the pretreated marc stream 4 and at least one stream of mixing liquid comprising a part juice 11 extracted from the band filter 7 downstream of the mixer 5.
    Block 7 operates the separation sub-step b2 with the band filter: it receives as input the flow of solid 6 which leaves the mixer of block 5, and at least one flow of washing liquid 8, with recycling of a part 11c of the juices extracted from downstream upstream of the filter and another part 11a towards the inlet of the mixer of block 5, there comes out a flow of washed solid 10.
    FIG. 5 represents the integration of the separation step b according to the invention into the complete process for the treatment of biomass according to a first variant in accordance with FIG. 4. After the blocks 2,5 and 7 already described, the new references have the following meaning:
    20. Stage (s) of production of biocatalysts which uses sweet juice 9
    21. Fluid flows necessary for the production of biocatalysts
    22. Solution containing biocatalysts (enzymes and / or yeasts), and possibly other fluids not shown
    23. Enzymatic hydrolysis step into which the other portion 4b of the pretreated marc 4 is introduced, and optionally the washed marc 10 (or enzymatic hydrolysis step and SSF simultaneous fermentation)
    24. Mixture of non-hydrolyzed solid and sugars from hydrolysis in solution (or mixture of non-hydrolyzed solid and fermentation product in the case of SSF)
    This figure therefore represents the invention this time integrated into the treatment process, which, beyond the pretreatment carried out on the biomass, continues with the enzymatic hydrolysis and fermentation of the marc.
    The pretreated marc 4 has been divided into a stream 4a which is separated according to the invention as described in the preceding figure, and a stream 4b which is directed to step 23 of enzymatic hydrolysis. Optionally, the separated and washed marc 10 according to the invention can also be directed to this step 23 with the flow 4b. (It can otherwise be valued differently, in the biomass treatment process or elsewhere). A flow 24 results therefrom which can, depending on whether the hydrolysis takes place simultaneously with the fermentation (SSF) or not, be composed of a mixture of non-hydrolysed solid and sugars resulting from the hydrolysis (without SSF) or d '' a mixture of non-hydrolyzed solid and fermentation products (with SSF).
    Block 20 is the stage (s) of production of the biocatalysts (enzymes, yeasts) which uses (s) the sweet juice 9 resulting from the separation by the band filter of block 7 and one or more fluid flows 21 necessary for the production biocatalysts (water, nutrient, other sugars, chemicals for example to regulate pH, etc.), this sweet juice 9 then serving as a growth / propagation or production substrate for the microorganisms (fungi) producing the enzymes and / or yeast.
    In this first variant, the extracted juice 9 is entirely used for the production of yeasts and / or enzymes. It can also be used for these purposes only for part of the stream 9. We can also recover all or part of this sweet juice 9 independently of the biomass treatment process (recover it as such, for example).
    It is also possible to subject all the pretreated marc to the separation operation according to the invention, and not to only a part thereof, then send all of the separated marc to the next block of enzymatic hydrolysis / fermentation. .
    It is also possible to directly use part of the raw marc (that is to say at the end of the pretreatment stage) for the production of enzymes and / or the propagation of yeasts. For the propagation of yeasts using marc from the biomass pretreatment, reference may be made, for example, to patent WO 2016/193576. For the production of enzymes using a pretreated marc, one can for example refer to patent WO 2017/174378.
    A flow 22 comes out of block 20 containing the biocatalysts (enzymes and / or yeasts), and possibly other fluids (for example: water, chemicals in particular for regulating the pH, etc.), biocatalysts if produced other than on juice sugar, nutrients, etc ...), this outgoing stream 22 being injected at the inlet of the block 23 of enzymatic hydrolysis.
    Once the production of enzymes has been carried out, either the whole must is exploited, that is to say both the enzymes and the fungi which produced them, or only the enzymes (we must then do a separation step / prior purification), to carry out the enzymatic hydrolysis of the pretreated biomass.
    Preferably, the enzyme cocktail was produced by a fungus Trichoderma reesei.
    As regards the production of yeasts, the yeast produced is preferably a yeast of the Saccharomyces cerevisiae type genetically modified to consume xylose. The flow obtained which will be used in the fermentation stage may contain the yeasts in whole or concentrated movement, in the latter case we speak of yeast cream (we must then carry out a prior concentration stage).
    FIG. 6 proposes to integrate in a second variant the separation step b of the invention. The new references have the following meaning:
    30. Fermentation step, for example in ethanol
    31. Fluid flow necessary for fermentation
    32. Solution containing the product of fermentation
    Here, there is therefore a block 30 of fermentation step distinct from step 23 of enzymatic hydrolysis, and the separation of blocks 5, 7 of the invention is inserted between these two stages: The stream 24 from the the enzymatic hydrolysis step is separated according to the invention, and the stream 9 at the outlet of the block 7 operating the separation by the band filter is sent as a stream entering the fermentation block 30, also supplied with an incoming stream 31 from or fluids necessary for fermentation, such as biocatalysts (yeasts), and possibly nutrients etc ...
    The stream 32 leaving the fermentation step contains the fermentation product, which can then undergo conventional separation steps, of the distillation, dehydration, solid / liquid separation type (not shown) which make it possible to obtain the desired biobased molecule ( here ethanol as biofuel), solid residues and liquid residues also called vinasses.
    FIG. 7 proposes to integrate in a third variant the separation step b of the invention. The new references have the following meaning:
    40. hydrolysis and fermentation stages
    41. Flux containing the non-hydrolyzed solid and the fermentation product
    42. flow of liquid solution containing the fermentation product
    50. Step of separation of the fermentation product
    51. Flow of purified fermentation product
    52. flow of vinasses
    Block 40 therefore represents the enzymatic hydrolysis step and the fermentation step which can be separated or simultaneous, represented by a common block for the sake of clarity. The stream 41 from these two stages and which therefore contains a portion of non-hydrolyzed solid and the fermentation product is brought into the inlet to the separation blocks 5, 7 according to the invention. The flow of liquid containing fermentation products leaving 42 from this separation feeds the block 50 of the step of separation of the fermentation products (this flow of liquid is therefore of different composition from flow 9 of the previous variants, which was only a juice sugar). At the outlet of block 50, a stream of liquid 51 of partially purified fermentation product is recovered, and a stream 52 of vinasses, which can optionally (dotted arrows in the figure) be recycled to replace the washing water 8 of the block filter of block 7.
    FIG. 8 proposes to integrate in a fourth variant the separation step b of the invention. The new references have the following meaning:
    54. medium separated from the product containing the non-hydrolyzed solid and the liquid
    55. vinasses
    Here, the separation step b of the invention is carried out after the separation step 50: the stream 54 resulting from the separation 50 and comprising a medium separated from the product containing the non-hydrolysed solid and the liquid is sent to the mixer 5, the flow of solid 55 leaving the band filter of the block 7 are vinasses extracted by washing therefore. In this variant, the separation step 50 can be coupled to the fermentation step, this is called fermentation / separation coupling, either in situ, in the fermentation reactor itself, or on another separate circuit, where the medium after separation returns to fermentation.
    In all these variants, it can be seen that the separation step b according to the invention can be inserted between known steps of a biomass treatment process, here to exploit the sweet juices as substrates for propagation, growth or production of enzymes of microorganisms necessary for the conversion of biomass, but also when we want to develop as such these sweet juices.
    Examples of realization
    They use the process diagrams and the tools detailed using the previous figures.
    Three examples will be described, on three different types of biomass: example 1 on TCR (Rapid Growth Coppice), example 2 on Miscanthus, and example 3 on straw.
    The objective is to obtain sweet juices J1 with a sugar concentration of 50 g / kg minimum.
    In the examples described below, the acronym MS designates the level of dry matter which is measured according to standard ASTM E1756-08 (2015) “Standard Test Method for Determination of Total Solids in Biomass”.
    The operating conditions are as follows:
    The M mixer is a PARIMIX IMR continuous mixer, which allows plumping of marc with high dry matter (MS) and solid content. It is heated by electrical means to about 40-50 ° C.
    The separation on the band filter F, of the continuous band filter type BFR from the company BHS with backwashing, makes it possible to extract juices concentrated in sugars. The band filter technology is based on vacuum filtration. The principle is to distribute the pretreated marc on a band advancing sequentially. This porous strip makes it possible, by vacuum drawing, to separate the liquids (the juices) from the solid by forming a cake (the washed marc), which falls at the end of the strip. The juices are partially recycled.
    The filter F used has 10 active vacuum zones, where different stages of the washing and filtration process can take place (zones that can be moved in the filter). The zones are grouped into three groups of zones, which are modular, and which make it possible to extract three juices J1, J2 and J3. The filter is provided, on the sides of the porous band, with polyurethane or silicone bands, to limit the vacuum losses observed and to improve the filtration of the product. The filter has a vertical wall above the strip just after the mixing feed area to allow better distribution of the mixture on the filter.
    To increase the recovery of soluble sugars and reduce the filtration time, the flows of recycled juices J2 (and J1 if applicable), J3 as well as the wash water F1 are heated:
    Juice J3 is heated and recycled to the first wash water nozzle f1
    The hot wash water supply was made by the second wash nozzle f2
    The J2 juice is heated and recycled until the pre-treated marc at the input of the mixer is replumped (and the J1 juice if applicable)
    For straw, part of the J1 juice was also recycled to the mixer M to increase the sugar concentration in the J1 juice.
    The characteristics of the filter and the operating conditions tested are as follows:
    Reference : BF025-020, Canvas : 058000-W120 (Polypropylene 120pm; 05-8000-S120) Material : polymer Debit : 180 kg / h of treatable suspension
    Filtration area: 0.5 m 2
    Vacuum level: between - 0.5 and -1 bar
    Table 1 below groups together the characteristics of solid content and dry matter content MS of the feed (pretreated biomass MO) which is separated according to the invention:
    Example 3: Straw Example 2: Miscanthus Example 1: TCR MO Pretreated Biomass 29 - 30% solid42 - 44% DM 42% solid54% DM 38 - 43% solid49-53% DM
    Table 1
    The speed of rotation of the feed screw of the mixer M, and therefore the flow rate of the pretreated marc MO, is defined by the frequency of the doser D. This speed influences the mixing and the consistency of the plumped marc at the outlet of the mixer. Too high a speed of the mixing screw results in a plump marc which is too viscous for the rest of the process. A weighing hopper is generally provided on the installation (not shown) and a means of measuring the marc flow rate, and the feed can be regulated by controlling the speed of the screw to this flow measurement. You can also choose to operate at a fixed speed of the screw, which will have been previously calibrated.
    Table 2 below shows the flow rates of raw marc and recycled juice entering the mixer:
    Gross input flow (kg / h) Recycled juice (kg / h) Straw 50 129 Miscanthus 70 95 TCR 50 75
    Table 2
    Example 1 according to the invention: Biomass based on fast growing coppice (TCR)
    Trials began with a TCR, often considered a difficult raw material to process. To improve the extraction, the sprinkler nozzles were installed, a vacuum of - 0.6 bar was assessed overall material and the operating conditions are detailed in table 3 above.
    Unit TCR Straw Miscanthus MO flow kg / h 50 50 70 Recycled J2 flow kg / h 75 110 90 Flow J1 recycled kg / h 0 20 0 Mixer outlet flow M kg / h 125 180 160 Progress time s 19 17 15 Vacuum pressure bar -0.6 -0.45 -0.15 Pressing pressure bar 3.3 3.7 2.6 Temperature J1) ° C 39 45 32 Debit kg / h 45 70 55 Temperature J2 after exchanger ° C 75 75 75 J2 flow produced kg / h 75 115 90 Temperature J3 after exchanger ° C 75 75 75 Flow J3 kg / h 60 105 80 Wash water flow kg / h 55 83 55 Wash water temperature ° C 50 50 50 Temperature M1 kg / h 40 35 45 M1 flow kg / h 60 52 92
    Table 3
    Example 2 according to the invention: Biomass based on Miscanthus
    The extraction of juice from the pretreated marc from Miscanthus was not a problem. Washing (also called mixing, done by mixer M) is very effective and juices with a sugar concentration between 58-60 g / kg have been produced. The overall material balance and the operating conditions are detailed in the preceding table, and in table 4 below.
    The band filter F was fed with 160 kg / h MoRe (18% DM) at 58 ° C. Two spill washing nozzles were installed in zones 4 and 6 of the 10 active zones of the strip. To have the greatest possible space between the flows, the first nozzle washed in counter-current mode of the advancement direction of the filter, and the second in co-current mode. 45 kg / h of juice J1 at 65-68 g / kg of sugars was produced during the first two days. Then, on the third day, the wash water flow was increased to produce more juice with a slightly lower concentration. Consequently, 55 kg / h of J1 was produced with a sugar concentration of between 58 and 60 g / kg.
    Example 3 according to the invention: Straw-based biomass
    The first test on the straw was made with the same configuration as for the two previous examples. As a result, J1 juice had a low sugar concentration of 38.77 g / kg. To increase it, a recycling of J1 (20 kg / h) to the tank of J2 was installed and the mixture of juices J1 and J2 was heated and recycled to the mixer M. To improve the vacuum and close the cake which tended to crack, the first washing nozzle was by spraying (zone 4) and the second by spillage (zone 6). Indeed, 70 kg / h of J1 juice at 53-57 g / kg of sugars was produced. The operating conditions are detailed in Table 4 above.
    To quickly check on site if the sugar concentration in the J1 juice reaches 50g / kg as requested, measurements were made with a PAL-1 refractometer from ATAGO.
    Table 4 below presents the loading characteristics: a mixture of MO with the juices J2 (or J1 + J2 for straw) and the products J1 and MO and quantifies the efficiency of the separation obtained with the invention: separation of the straw was the most efficient (99%).
    Ex 3: Straw Ex 2: Miscanthus Ex 1: TCR Charge MO pretreated biomass 29 - 30% solid42 - 44% DM~ 90 g / kg of sugar 42% solid54% DM~ 95 g / kg of sugar 38 - 43% solid49 - 53% DM~ 83 g / kg of sugar J2 recycled juice ~ 0.003% solid6% DM~ 33 g / kg of sugar ~ 0% solid4% DM~ 27 g / kg of sugar ~ 0% solid8.6% DM~ 50 g / kg of sugar MORe pretreated biomass 8.5% solid16% DM 18% solid26% DM 16% solid25% DM Product J1 ~ 0.03% solid9 -10% DM53 - 57 g / kg of sugar ~ 0.09% solid9 -10% DM58 - 60 g / kg of sugar ~ 0.07% solid11% DM69 - 70 g / kg of sugar M1 30 - 32% solid32 - 33% DM0.3 - 1 g / kg of sugar 31 - 33% solid37 - 38% DM32-38 g / kg sugar 33 - 34% solid35 - 37% DM13-20 g / kg of sugar Separation efficiency E 99% ~ 62% ~ 79%
    Table 4
    In conclusion, it can be seen that these three examples according to the invention, with different initial biomasses, manage to achieve the objective of an extracted juice J1 with the desired sugar concentration, 5 significantly above the minimum threshold of 50 g / kg. The separation according to the invention with the two tools in series, continuous mixer and continuous (belt) filter allows a lot of flexibility, and a great compactness. They can therefore be inserted without difficulty in a biomass treatment installation at different stages, as soon as there is a need to effect a solid / liquid separation on a mixture while wishing to recover both the solid part and the liquid part obtained after 10 separation.
    The invention thus makes it possible, whatever the pretreated biomass and its rheological constraints, to obtain a sweet juice of a concentration greater than 50 g / kg, which is not the case when the invention is not implementation, as shown in the following comparative examples:
    Comparative examples (not in accordance with the invention):
    The pretreated biomasses of two of the preceding examples are used in a configuration not in accordance with the invention: the substrate MO is mixed in a mixer M with water and then separated on the band filter F. In this implementation not in accordance with the invention, there is no recycling of a stream extracted from the band filter F to the mixer M.
    Comparative Example 4: Biomass Based on TCR
    The pretreated MO TCR biomass from example 1 is mixed in a mixer M with water and then separated on the band filter F itself operated according to the configuration of example 1. By its rheology, the biomass TCR pretreated must be diluted to a solids content of less than 16% to form a cake capable of being filtered on the band filter F. The composition of the TCR marc MO of example 1 is recalled: solid content 38%, sugar content 83 g / kg. To obtain a correct rheology at the mixer outlet, it is necessary to lower the solid content of the substrate after mixing, it is therefore necessary to add 68.8 kg of water to 50 kg of marc marc in the mixer, this mixture is then deposited on the belt filter. The first zone of the belt filter allows to extract a concentrated juice J1 with a content of 41.6 g / kg of sugars only. In this example not in accordance with the invention, it can be seen that it is not possible to reach a concentration of 50 g / kg of sugars in the juice J1 for the substrate TCR.
    Comparative Example 5: Biomass Based on Straw
    The MO straw pretreated biomass from Example 3 is mixed in a mixer M with water and then separated on the band filter F itself operated according to the configuration of Example 3. By its rheology, the biomass Straw pretreated must be diluted to a solids level of less than 9% to form a cake capable of being filtered on the band filter F. The composition of the straw marc of straw from Example 3 is recalled: solid content 30%, sugar content 90 g / kg. To obtain a correct rheology at the mixer outlet, it is necessary to lower the solid content of the substrate after mixing, it is therefore necessary to add 117 kg of water to 50 kg of marc marc in the mixer, this mixture is then deposited on the band filter. The first zone of the band filter allows to extract a concentrated juice J1 with a content of 27 g / kg of sugars. In this example not in accordance with the invention, it can be seen that it is not possible to reach a concentration of 50 g / kg of sugars in the juice J1 for the straw substrate.
    权利要求:
    Claims (15)
    [1" id="c-fr-0001]
    1. Method for treating a lignocellulosic biomass, said method comprising at least the following step:
    at. Pretreatment of the biomass by at least one cooking or steam explosion operation, in order to obtain a pretreated substrate, characterized in that it also comprises at least one step of:
    b. Liquid / solid separation on at least part of the pretreated substrate obtained at the end of step a or at the end of an additional step of treatment of said substrate after step a, said separation step comprising two sub- successive steps:
    - an upstream sub-step of contacting b1 of the solid / liquid mixture implemented by a continuous mixer (M) using a mixing fluid, possibly preceded by a pump, and
    - a downstream extraction / washing sub-step b2 implemented by a continuous filter, in particular a band filter (F), using a washing fluid, to obtain a solid phase enriched in solid and a plurality of liquid phases enriched in liquid, with at least partial recycling of a liquid phase extracted from the filter at the inlet of the mixer as a mixing fluid.
    [2" id="c-fr-0002]
    2. Method according to the preceding claim, characterized in that the continuous filter operates against the current between the circulation of the solid / liquid mixture to be separated and the extraction / washing fluid.
    [3" id="c-fr-0003]
    3. Method according to one of the preceding claims, characterized in that the separation of the solid / liquid mixture is carried out during step b on a first part of the pretreated substrate obtained at the end of step a, in that a second part of said pretreated substrate is subjected to at least one subsequent treatment step, in particular a hydrolysis, and that the solid phase enriched in solid obtained in step b is also subjected to at least one subsequent step treatment, including the same or the same as those undergone by the second part of the pretreated substrate.
    [4" id="c-fr-0004]
    4. Method according to one of the preceding claims, characterized in that it comprises a step e of enzymatic hydrolysis of the pretreated substrate from step a of pretreatment to obtain a hydrolyzate, in that the solid separation is carried out / liquid b on at least part of said hydrolyzate.
    [5" id="c-fr-0005]
    5. Method according to one of the preceding claims, characterized in that the solid / liquid separation b is carried out on at least part, in particular all, of the pretreated substrate obtained at the end of the pretreatment step a to obtain a solid phase enriched in solid, and in that it comprises a step e of enzymatic hydrolysis of said solid phase enriched in solid to obtain a hydrolyzate.
    [6" id="c-fr-0006]
    6. Method according to one of the preceding claims, characterized in that the liquid phases enriched in liquid resulting from the separation step b are sweet juices, in that said method also comprises a step c of production of enzymes and / or a step d for the production of yeasts, and in that at least one of said sweet juices is used for said production of enzymes c or of yeasts d.
    [7" id="c-fr-0007]
    7. Method according to one of the preceding claims, characterized in that it also comprises the following steps after step a of pretreatment:
    e. Enzymatic hydrolysis of the pretreated substrate, in order to obtain a hydrolyzate comprising a solid matter and a liquid phase containing sugars,
    f. Fermentation of the hydrolyzate, in order to obtain a fermentation wine, stage f of fermentation being able to succeed or be concomitant with stage e of enzymatic hydrolysis
    g. Separation / distillation of fermentation wine, in order to obtain a distillation product in the form of an alcohol, a solvent, or other biobased molecule, and vinasses, step b being carried out on at least part of the products obtained after step e of hydrolysis and / or f of fermentation and / or g of separation / distillation.
    [8" id="c-fr-0008]
    8. Method according to one of the preceding claims, characterized in that, in step b of separation, the extraction / washing fluid is heated before introduction into the filter (F) and / or the liquid phase extracted from the filter and recycled before its introduction into the mixer, in particular at a temperature of at least 30 ° C, in particular of at most 90 ° C, in particular a temperature between 40 ° C and 80 ° C.
    [9" id="c-fr-0009]
    9. Method according to one of the preceding claims, characterized in that, in step b, the filter is a band filter (F) which comprises at least two, in particular at least three, successive zones, with withdrawal in each liquid phase area.
    [10" id="c-fr-0010]
    10. Method according to the preceding claim, characterized in that the liquid phase of the first and / or of the second zone is recycled at least in part at the inlet of the mixer (M) of step b, and in that the phase liquid withdrawn from the third and / or last zone is recycled at least in part as washing / extraction fluid from the belt filter (F).
    [11" id="c-fr-0011]
    11. Method according to one of the preceding claims, characterized in that the operating parameters of the separation steps b1 and b2 are selected according to the characteristics of the solid / liquid mixture so that the liquid phases produced extracted from the band filter ( F) have a concentration of at least 50 g of product / kg, in particular at least 50 g of sugar / kg when the separation b is carried out on the pretreated substrate obtained from step a of pretreatment.
    [12" id="c-fr-0012]
    12. Installation for processing a lignocellulosic biomass, characterized in that it comprises at least:
    - a biomass pretreatment zone by at least one cooking or steam explosion operation, in order to obtain a pretreated substrate,
    a liquid / solid separation zone on at least part of the pretreated substrate obtained at the exit from the pretreatment zone or from an additional zone for treating said substrate after the pretreatment zone, said separation zone comprising two sub-zones in series: - an upstream contacting sub-zone comprising a continuous mixer (M) using a mixing fluid, possibly associated with an upstream pump, and - a downstream extraction / washing sub-zone comprising a continuous filter, in particular a band filter (F), with a washing fluid, with an operation of the filter preferably in counter-current between the circulation of the solid / liquid mixture to be separated and the extraction / washing fluid, and at least partial recycling a liquid phase extracted by the filter at the inlet of the mixer as a mixing fluid.
    [13" id="c-fr-0013]
    13. Treatment installation according to the preceding claim, characterized in that it provides, in the separation zone: - fluid connection means between the filter (F) and the mixer (M) to recycle at least part of a liquid phase extracted by the filter at the inlet of the mixer and - fluid connection means for recycling another liquid phase extracted from the filter (F) as washing fluid for said filter.
    [14" id="c-fr-0014]
    14. Treatment installation according to one of claims 12 or 13, characterized in that it also comprises an enzyme production zone and / or a yeast production zone, and in that it provides a means of transfer of at least one liquid phase extracted from the band filter from the separation zone to the enzyme production zone and / or to the yeast production zone, said liquid phase being a sweet juice.
    [15" id="c-fr-0015]
    15. Use of the method or the installation according to one of the preceding claims for the treatment of biomass of wood, straw, agricultural residues and all dedicated energy crops, in particular annual or multi-annual plants such as miscanthus in view to produce sugars, biofuels or biobased molecules.
    类似技术:
    公开号 | 公开日 | 专利标题
    EP3484945B1|2020-06-03|Method for treating lignocellulosic biomass by impregnation and steam explosion
    EP3587583A1|2020-01-01|Method for processing lignocellulosic biomass
    EP2430171B1|2015-04-01|Method for producing alcohols and/or solvents from lignocellulosic biomass with acid recycling of solid residues
    US20110281298A1|2011-11-17|Method and apparatus to extracted and reduce dissolved hemi-cellulosic solids in biomass following pre-hydrolysis
    EP2516661B1|2016-07-20|Method for producing alcohols and/or solvents from paper pulps with recycling of the non-hydrolysated plant material in a regeneration reactor
    WO2014135755A1|2014-09-12|Method for producing alcohols and/or solvents from lignocellulosic biomass with washing of the solid residue obtained after fermentation
    EP3728410B1|2021-10-06|Lignocellulosic biomass treatment method
    WO2011086245A2|2011-07-21|Method for producing alcohols and/or solvents from paper pulps with recycling of the non-hydrolysated plant material
    EP3728408B1|2021-10-06|Method for treating lignocellulosic biomass by impregnation
    WO2020126918A1|2020-06-25|Method for cleaning a reactor for processing a lignocellulosic biomass
    FR3037075A1|2016-12-09|PROCESS FOR THE PRETREATMENT OF BIOMASS FOR ITS GASIFICATION, ESPECIALLY FOR THE PRODUCTION OF SECOND GENERATION SYNTHESIS FUELS
    EP3728409B1|2021-10-06|Method for treating lignocellulosic biomass
    CA3119407A1|2020-06-25|Process for treating lignocellulosic biomass
    CA3119406A1|2020-06-25|Method for cleaning a reactor for processing a lignocellulosic biomass
    CA3125497A1|2020-07-30|Method for treating a lignocellulosic biomass
    同族专利:
    公开号 | 公开日
    MX2019007408A|2020-01-23|
    AU2019204400A1|2020-01-16|
    FR3083126B1|2020-06-26|
    JP2020000230A|2020-01-09|
    BR102019013159A2|2020-07-07|
    AR115615A1|2021-02-10|
    CA3047963A1|2019-12-27|
    US20200002482A1|2020-01-02|
    EP3587583A1|2020-01-01|
    CN110643642A|2020-01-03|
    ZA201904073B|2020-12-23|
    引用文献:
    公开号 | 申请日 | 公开日 | 申请人 | 专利标题
    EP2471940A1|2010-12-31|2012-07-04|Süd-Chemie AG|Efficient lignocellulose hydrolysis with integrated enzyme production|
    EP2860269A1|2012-05-18|2015-04-15|Toray Industries, Inc.|Method for producing sugar solution|
    FR2991997A1|2012-06-18|2013-12-20|IFP Energies Nouvelles|PROCESS FOR PRODUCING AN ENZYMATIC COCKTAIL USING THE LIQUID RESIDUES OF A PROCESS FOR BIOCHEMICAL CONVERSION OF LIGNOCELLULOSIC MATERIALS|
    WO2014091103A1|2012-12-14|2014-06-19|IFP Energies Nouvelles|Method for producing solutions of sugars and alcohols from lignocellulosic biomass with complementary treatment of the solid residue by a hydrated inorganic salt|
    WO2016124822A1|2015-02-06|2016-08-11|Upm-Kymmene Corporation|A method and an apparatus for increasing concentration of soluble carbohyrate containing fraction, a soluble carbohyrate containing fraction, a solid fraction and their use|
    FR3043408A1|2015-11-09|2017-05-12|Ifp Energies Now|PROCESS FOR THE TREATMENT OF LIGNOCELLULOSIC BIOMASS INCLUDING THE GASIFICATION OF A POWDER OF A WOOD RESIDUE FROM A BIOCHEMICAL PROCESS FOR THE TREATMENT OF LIGNOCELLULOSIC BIOMASS|
    FR3002950B1|2013-03-06|2016-03-11|Ifp Energies Now|PROCESS FOR PRODUCING ALCOHOLS AND / OR SOLVENTS FROM LIGNOCELLULOSIC BIOMASS WITH WASHING OF THE SOLID RESIDUE OBTAINED AFTER HYDROLYSIS|
    FR3002949B1|2013-03-06|2016-09-16|Ifp Energies Now|PROCESS FOR PRODUCING ALCOHOLS AND / OR SOLVENTS FROM LIGNOCELLULOSIC BIOMASS WITH WASHING OF THE SOLID RESIDUE OBTAINED AFTER FERMENTATION|
    FR3036709B1|2015-05-29|2019-06-07|Lesaffre Et Compagnie|PROPAGATION OF YEAS SIMULTANEOUS TO SACCHARIFICATION|
    FR3049957B1|2016-04-08|2020-09-25|Ifp Energies Now|PROCESS FOR THE PRODUCTION OF CELLULASES WITH PRETREATED LIGNOCELLULOSIC MARK|FR3095649A1|2019-05-03|2020-11-06|Europeenne De Biomasse|Pulverulent substrate obtained by steam cracking of a biomass without chemical auxiliary and its uses|
    FR3111643A1|2020-06-22|2021-12-24|IFP Energies Nouvelles|PROCESS FOR THE PRODUCTION OF PROTEINS, SUGARS, ALCOHOL, BY A STRAIN OF TRICHODERMA MUSHROOM IN WHICH THE CEL1A GENE IS INVALID|
    法律状态:
    2019-06-25| PLFP| Fee payment|Year of fee payment: 2 |
    2020-01-03| PLSC| Search report ready|Effective date: 20200103 |
    2020-06-26| PLFP| Fee payment|Year of fee payment: 3 |
    2020-12-11| CD| Change of name or company name|Owner name: INSTITUT NATIONAL DE RECHERCHE POUR L'AGRICULT, FR Effective date: 20201103 Owner name: AGRO INDUSTRIES RECHERCHE ET DEVELOPPEMENT, FR Effective date: 20201103 Owner name: IFP ENERGIES NOUVELLES, FR Effective date: 20201103 |
    2021-06-25| PLFP| Fee payment|Year of fee payment: 4 |
    优先权:
    申请号 | 申请日 | 专利标题
    FR1855789|2018-06-27|
    FR1855789A|FR3083126B1|2018-06-27|2018-06-27|LIGNO-CELLULOSIC BIOMASS TREATMENT PROCESS|FR1855789A| FR3083126B1|2018-06-27|2018-06-27|LIGNO-CELLULOSIC BIOMASS TREATMENT PROCESS|
    EP19178488.3A| EP3587583A1|2018-06-27|2019-06-05|Method for processing lignocellulosic biomass|
    MX2019007408A| MX2019007408A|2018-06-27|2019-06-20|Method for treating lignocellulosic biomass.|
    ARP190101749A| AR115615A1|2018-06-27|2019-06-24|METHOD TO TREAT LIGNOCELLULOSIC BIOMASS|
    AU2019204400A| AU2019204400A1|2018-06-27|2019-06-24|Method for treating lignocellulosic biomass|
    JP2019116111A| JP2020000230A|2018-06-27|2019-06-24|Method of treating lignocellulosic biomass|
    ZA2019/04073A| ZA201904073B|2018-06-27|2019-06-24|Method for treating lignocellulosic biomass|
    BR102019013159-4A| BR102019013159A2|2018-06-27|2019-06-25|lignocellulosic biomass treatment process|
    CA3047963A| CA3047963A1|2018-06-27|2019-06-25|Ligno cellulosic biomass treatment process|
    US16/451,946| US20200002482A1|2018-06-27|2019-06-25|Method for treating lignocellulosic biomass|
    CN201910567003.6A| CN110643642A|2018-06-27|2019-06-27|Method for treating lignocellulosic biomass|
    [返回顶部]